Unusual Gold(I)-Catalyzed Isomerization of 3-Hydroxylated 1,5-Enynes: Highly Substrate-Dependent Reaction Manifolds
- 18 August 2005
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 7 (19) , 4129-4132
- https://doi.org/10.1021/ol051397k
Abstract
The gold(I) isomerization of diversely substituted 3-hydroxylated enynes has led to the discovery of three new unreported skeletal rearrangements furnishing structures such as alkylidene-cyclopentenes, cyclohexadienes or α,β-unsaturated aldehydes under very mild conditions.Keywords
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