Yet another direct measurement of the rate constant for the recombination of methyl radicals
- 1 November 1974
- journal article
- research article
- Published by Wiley in International Journal of Chemical Kinetics
- Vol. 6 (6) , 887-891
- https://doi.org/10.1002/kin.550060611
Abstract
The decaying absorption of CH3 radicals at 216.4 nm has been followed over more than three half‐lives using a photoelectric split‐beam kinetic spectrometer. The rate constant for recombination kr was found to be (5.60 ± 0.76) × 10−11 cm3/molecule·s.Keywords
This publication has 10 references indexed in Scilit:
- The methyl radical combination rate constant as determined by kinetic spectroscopyInternational Journal of Chemical Kinetics, 1973
- Methyl‐radical association studied by time‐resolved mass spectroscopyInternational Journal of Chemical Kinetics, 1973
- Direct measurement of the rate of reaction of the methyl radical with sulphur dioxideJournal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1973
- Flash Photolysis of Ketene and Diazomethane: The Production and Reaction Kinetics of Triplet and Singlet MethyleneThe Journal of Chemical Physics, 1970
- A Quantitative study of alkyl radical reactions by kinetic spectroscopy. Part I. Mutual combination of methyl radicals and combination of methyl radicals with nitric oxideInternational Journal of Chemical Kinetics, 1970
- An experimental determination of the oscillator strength of the 2160Å band of the free methyl radical and a spectroscopic measurement of the combination rateChemical Physics Letters, 1969
- Rate parameters for reactions of O(23 P) with CS2, NO2 and olefinsTransactions of the Faraday Society, 1968
- Photolysis by pulsed illuminationProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1963
- Rate of Recombination of Radicals. I. A General Sector Theory; A Correction to the Methyl Radical Recombination RateThe Journal of Chemical Physics, 1956
- ABSORPTION SPECTRUM OF FREE CH3 AND CD3 RADICALSCanadian Journal of Physics, 1956