The electronic properties and stereochemistry of the copper(II) ion. Part IV. Some diammine complexes
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 2578-2583
- https://doi.org/10.1039/j19680002578
Abstract
The electronic, e.s.r., and i.r. spectra of a number of diammine complexes of copper(II) are reported. For complexes of known crystal structure the electronic properties are correlated with the local copper(II) environment present, namely trigonal bypyramidal, square-based pyramidal, rhombic, and reversed tetragonal. These correlations are then used to suggest the local copper(II) ion stereochemistry in a series of diamminecopper(II) complexes of unknown crystal structure.Keywords
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