The inherent instability of dimethylformamide–water systems containing hydroxide ion
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 3,p. 164-165
- https://doi.org/10.1039/c29700000164
Abstract
Aqueous dimethylformamide (DMF) solutions containing hydroxide ion are unstable, formate ion and dimethylamine being produced fairly rapidly even under mild conditions, with a maximum rate constant at ca. 30 mole% DMF.Keywords
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