Roles of the lower and the upper Hubbard bands and the donor-excitonic states in the theory of shallow-impurity states in doped semiconductors

Abstract
A self-consistent unrestricted Hartree-Fock pseudocluster calculation has been performed to investigate the roles of various bands in doped semiconductors. While the lower and the upper Hubbard bands of the Mott-Hubbard-Anderson (MHA) model are well defined at low concentration, the donor-excitonic states are important at higher concentration where the upper Hubbard band is pushed into the conduction band. The so modified MHA model can still explain almost all the experimental results.

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