Synthesis of Biaryls by Intramolecular Radical Transfer in Phosphinates
- 7 August 2001
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 66 (18) , 6083-6091
- https://doi.org/10.1021/jo010371d
Abstract
Phosphinates 20a−35a give biaryls 20b−35b on heating with stannanes in the presence of AIBN. The process involves a radical ipso substitution on the migrating aryl ring.Keywords
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