Organometallic derivatives. Part VI. Synthesis and reactivity of some (ferrocenylmethyl)phosphines
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 1955-1958
- https://doi.org/10.1039/p19730001955
Abstract
(Ferrocenylmethyl)phosphines have been prepared by the reactions of phenylphosphine. diphenylphosphine, and diphenylphosphine oxide with dimethylaminomethylferrocene methiodide. A series of α-substituted ferrocenyl-methyl alcohols have been treated with phenylphosphine and diphenylphosphine. In these reactions the phosphine behaves both as a nucleophile. displacing the hydroxy-group to give a (ferrocenylmethyl)phosphine, and as a reducing agent, giving the corresponding ferrocenylalkane.Keywords
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