Reactions of oximes and diethylhydroxylamine with titanium alkoxides

1 January 1971

journal article
research article
Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A

p. 2440-2444
https://doi.org/10.1039/j19710002440

Abstract

Alkoxides of titanium react exothermally with oximes and diethylhydroxylamine to give complexes of the formula, Ti(OR)_4–x(L)_x[x= 1–4; R = Prⁱ when LH = oxime; R = Et, Prⁱ, and Bu^t when LH = Et₂NOH]. Alcoholysis of some of these give the corresponding t-butoxy-derivatives. I.r. spectra have been recorded and molecular weights determined.

Keywords

DIETHYLHYDROXYLAMINE
TITANIUM
ALKOXIDES
OXIMES
REACT
CORRESPONDING
BUTOXY
ALCOHOLYSIS
I.R
SPECTRA

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