Rational construction of mixed-metal alkoxides
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1750-1751
- https://doi.org/10.1039/c39900001750
Abstract
The acidic protons in Zr2(OR)8(ROH)2, R = Pri, serve as a controlled functionality and react with Ba metal and with LiNMe2 to give the hydrocarbon-soluble heterometallic alkoxides Ba2Zr4(OR)20 and LiZr2(OR)9(ROH) which have been characterized in solution by NMR spectroscopy and in the solid state by X-ray diffraction: Zr2(OR)9 units bind the Li+ and Ba2+via bridging alkoxides and, for Li+, a terminal alcohol ligand which hydrogen bonds to a terminal alkoxide on zirconium.Keywords
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