Conformational equilibria and barriers to rotation in monohalogenobutanes with methyl substituents. Methyl–halogen interactions. The size of a halogen atom
- 1 January 1976
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 2
- No. 3,p. 336-341
- https://doi.org/10.1039/p29760000336
Abstract
An n.m.r. study of barriers to rotation and conformational equilibria in 2-halogeno-2, 3, 3-trimethylbutanes and 2-halogeno-2, 3-dimethylbutanes is reported. Results are discussed in terms of the steric requirement of halogen atoms, and the interaction of these atoms with adjacent methyl groups.Keywords
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