Thermal Alkane C−H Bond Activation by a Tungsten Alkylidene Complex: The Reversal of α-Hydrogen Elimination
- 1 May 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 119 (21) , 5071-5072
- https://doi.org/10.1021/ja9704850
Abstract
No abstract availableThis publication has 20 references indexed in Scilit:
- Unusual Ligand-Induced Reductive Elimination in Cp*W(NO)(H)[η2-PPh2C6H4]: A Route to the Extremely Strong π-Donor Fragment Cp*W(NO)(PPh3)Journal of the American Chemical Society, 1997
- σ-Bond Metathesis Reactions of Sc(CH3)2+ with Secondary C−H Bonds: Reactivity with Cyclohexane and CyclopentaneOrganometallics, 1996
- Novel Synthetic Routes to the Anionic Alkylidene Complex [Cp*Mo(NO)(CH2SiMe3)(CHSiMe3)]- from Its Neutral Dialkyl PrecursorOrganometallics, 1996
- Syntheses and Structures of Unsymmetrically 1,1- and 1,2-Disubstituted Alkene Complexes of the Chiral Rhenium Lewis Acid [(.eta.5-C5H5)Re(NO)(PPh3)]+: Enantioface Binding Selectivities and Conformational EquilibriaOrganometallics, 1994
- Monomeric and dimeric zirconocene imido compounds: synthesis, structure, and reactivityOrganometallics, 1993
- Thermal chemistry of molybdenum complex CpMo(NO)(CH2CMe3)2: Lewis base adducts of CpMo(NO)(:CHCMe3) and a new bonding mode for nitric oxideOrganometallics, 1993
- Organometallic nitrosyl chemistry. 57. Synthesis and characterization of the asymmetric complexes Cp*W(NO)(R)(R') [R,R' = alkyl, aryl] and regioselective insertions of CO into their W-C .sigma. bondsOrganometallics, 1993
- Organometallic nitrosyl chemistry. 52. A unique .mu.-.eta.1:.eta.2-NO ligand in a bimetallic alkylidene nitrosyl complex of molybdenumJournal of the American Chemical Society, 1992
- Effect of ligand asymmetry on the structure and reactivity of CpMLL'(allyl) (Cp = cyclopentadienyl, M = metal, L = ligand) and -(ethylene) complexesJournal of the American Chemical Society, 1979
- Alkylcarbene complex of tantalum by intramolecular .alpha.-hydrogen abstractionJournal of the American Chemical Society, 1974