An Azacyclophane Derivative as Catalyst of Substrate‐ and Product‐Selective Reactions with Ambident Anions
- 1 November 1984
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 23 (11) , 911-912
- https://doi.org/10.1002/anie.198409111
Abstract
An increase in reaction rate and alteration of the product ratioin nucleophilic exchange reactions is achieved when the azacyclophane1described in the two previous communications is added to the reaction of ambident nucleophiles with 2‐bromomethylnaphthalene. Similarly as in the case of enzymes, saturation kinetics and competitive inhibition are observed as well as substrate and product selectivity.Keywords
This publication has 11 references indexed in Scilit:
- Structure‐ and Solvent‐Dependence in the Complexation of Lipophilic Substrates in a Water‐Soluble AzacyclophaneAngewandte Chemie International Edition in English, 1984
- Dünnschichtchromatographie mit einem immobilisierten Azacyclophanderivat als analytisches Hilfsmittel und als Sonde für Wirt‐Gast‐WechselwirkungenAngewandte Chemie, 1984
- Struktur‐ und Lösungsmittelabhängigkeiten bei der Komplexierung lipophiler Substrate in einem wasserlöslichen AzacyclophanAngewandte Chemie, 1984
- Thin Layer Chromatography with an Immobilized Azacyclophane Derivative as Analytical Agent and Probe for Host‐Guest InteractionsAngewandte Chemie International Edition in English, 1984
- Macrocyclische quartäre Ammoniumsalze, IV1). Katalyse von nucleophilen aromatischen Substitutionen mit Azid als NucleophilEuropean Journal of Inorganic Chemistry, 1984
- Artificial EnzymesScience, 1982
- BIOMIMETIC CHEMISTRYPublished by Elsevier ,1982
- Macrotricyclic Quaternary Ammonium Salts: Enzyme‐Analogous ActivityAngewandte Chemie International Edition in English, 1981
- Makrotricyclische quartäre Ammoniumsalze: Enzymanaloge AktivitätAngewandte Chemie, 1981
- Modified crown ether catalysts. 3. Structural parameters affecting phase transfer catalysis by crown ethers and a comparison of the effectiveness of crown ethers to that of other phase transfer catalystsJournal of the American Chemical Society, 1980