Total synthesis of cis-maneonenes-a and -b
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 415-417
- https://doi.org/10.1039/c39830000415
Abstract
The first syntheses of Laurencia-derived cyclic ethers containing terminal cis-enyne side chains are reported which employ (for the first time in complex natural product synthesis) a recently developed partial catalytic hydrogenation of a silylated butadiyne derivative which, in turn, is derived from bis(trimethylsilyl)butadiyne.Keywords
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