A possible azirine intermediate in the reaction of bromonitroalkenes with triphenylphosphine
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 15,p. 917-918
- https://doi.org/10.1039/c29700000917
Abstract
Bromonitroalkenes react with triphenylphosphine in benzene to give α-cyanoalkyltriphenylphosphonium bromides: the same reaction in methanol gives a rearranged product (IV), the formation of which is most easily rationalised via an azirine intermediate.Keywords
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