A projector formulation for the Van Vleck transformation
- 1 November 1975
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 30 (5) , 1377-1395
- https://doi.org/10.1080/00268977500102911
Abstract
The Van Vleck transformation as previously described is generalized so that it can isolate several levels simultaneously. It is shown that the contact transformation involves projectors in an implicit way and that it can be considered as a special case of the generalized Van Vleck transformation. We discuss to what extent the recursion relations (for further transformation of the Nth transform) given in part I can be carried over to the generalized Van Vleck transformation and to the contact transformation. An effective hamiltonian for a particular ‘cluster’ of zeroth-order levels can be obtained in several ways. We compare the results of the usual Van Vleck transformation, Soliverez's transformation and the contact transformation.Keywords
This publication has 16 references indexed in Scilit:
- Effective hamiltoniansMolecular Physics, 1975
- Construction of model hamiltonians in framework of Rayleigh-Schrödinger perturbation theoryCzechoslovak Journal of Physics, 1974
- A projector formulation for the Van Vleck transformationMolecular Physics, 1974
- A projector formulation for the Van Vleck transformationMolecular Physics, 1974
- An effective Hamiltonian and time-independent perturbation theoryJournal of Physics C: Solid State Physics, 1969
- Sur la théorie des perturbations des états liésNuclear Physics, 1958
- The Rotation-Vibration Energies of Tetrahedrally Symmetric Pentatomic Molecules. IPhysical Review B, 1939
- The Vibration-Rotation Energy Levels of Polyatomic Molecules I. Mathematical Theory of Semirigid Asymmetrical Top MoleculesThe Journal of Chemical Physics, 1936
- The Effect of Crystalline Electric Fields on the Paramagnetic Susceptibility of Cupric SaltsPhysical Review B, 1934
- On-Type Doubling and Electron Spin in the Spectra of Diatomic MoleculesPhysical Review B, 1929