A Thermodynamic Study of the Tin-Antimony System
- 1 January 1945
- journal article
- Published by The Electrochemical Society in Transactions of The Electrochemical Society
- Vol. 88 (1) , 243-251
- https://doi.org/10.1149/1.3071686
Abstract
The determination of the thermodynamic properties of metallic solutions has been greatly facilitated by the application of electromotive force measurements obtained from concentration cells involving a pure metal and alloys of that metal. The technic used in obtaining the experimental data for this paper was similar to the method outlined by Seltz. Activities, relative partial molal and total relative heat contents, free energy changes and entropies are evaluated for both components and for the system over the complete concentration range at 905.1° K. It is shown that solutions of tin‐antimony at 905.1° K exhibit Hilde‐ brand “regular” solution behavior.Keywords
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