Photoelectron spectrum of 5-methylenenorborn-2-ene and through-space interactions (homobutadiene conjugation)

1 January 1973

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 17,p. 627-628
https://doi.org/10.1039/c39730000627

Abstract

The photoelectron spectra of 5-methylenenorborn-2-ene (I), 2-methylenenorborane (III), and norbornene show that the π-orbitals in the diene (I) interact strongly but the interacation leads to little or no stabilization of the π-system; simple HMO arguments and consideration of the photoelectron spectrum of norbornadiene (II) suggest that the interaction is mostly π-bonding through-space.

Keywords

SPECTRUM