Magnesium Bisamides as Reagents in Synthesis
- 27 July 2001
- journal article
- concept
- Published by Wiley in Chemistry – A European Journal
- Vol. 7 (16) , 3430-3437
- https://doi.org/10.1002/1521-3765(20010817)7:16<3430::aid-chem3430>3.0.co;2-1
Abstract
As part of the continued requirement for more selective reagents in organic synthesis, magnesium bisamides are becoming established as a class of organometallic bases with considerable potential. Their relatively mild reactivity, combined with their high degree of steric congestion, leads to a distinct class of reagents with significantly different chemo‐, regio‐, stereo‐ and enantioselectivities when compared with existing species and protocols.Keywords
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