α-PHOSPHORYL SULFOXIDES.V.1,2SYNTHESIS AND CRYSTAL AND MOLECULAR STRUCTURE OF O,O-DIPHENYLPHOSPHORYL-METHYL PHENYL SULFOXIDE
- 1 May 1987
- journal article
- research article
- Published by Taylor & Francis in Phosphorus and Sulfur and the Related Elements
- Vol. 31 (1-2) , 19-25
- https://doi.org/10.1080/03086648708079337
Abstract
The crystal structure of the title compound (1) was determined by X-ray diffraction technique from diffractometer intensity measurements; C19H17O4PS, triclinic space group P1, a=9.4630(6), b=9.8814(6), c=10.2977(5)°, α=84.37(4), β=84.59(5), γ=70.40(4)°, 2998 reflections, R=0.0402. The molecule of 1 adopts a conformation in which the diphenoxyphosphoryl and phenyl groups are in antiperiplanar orientation around the sulfur-methylene carbon bond.Keywords
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