High-valent dioxo-ruthenium(VI) complexes of macrocyclic tetradentate tertiary amines: X-ray crystal structures of trans-[Ru VI (15-tmc)O2](ClO4)2(15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[Ru VI (16-tmc)O2](ClO4)2(16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane)
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 986-988
- https://doi.org/10.1039/c39850000986
Abstract
The X-ray crystal structures of trans-[RuVI(15-tmc)O2](ClO4)2(15-tmc = 1,4,8,12-tetramethyl-1,4,8,12-tetra-azacyclopentadecane) and trans-[RuVI(16-tmc)O2](ClO4)2(16-tmc = 1,5,9,13-tetramethyl-1,5,9,13-tetra-azacyclohexadecane) have been determined; the RuO bond distances in these two complexes, 1.718(5) and 1.705(7)Å respectively, appear to be insensitive to the ring size of the macrocycle.Keywords
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