Rhodium(III) alkyls stabilized by a quadridentate Schiff-base ligand
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 19,p. 1262-1263
- https://doi.org/10.1039/c29700001262
Abstract
RhCl(salen)(py) is reduced by sodium amalgam or NaBH4 in alkaline solution to give compounds which react with alkyl halides to yield the alkyls RhR(salen)(py)(R = Me or Et); reduction of the chloro-complex with zinc amalgam gives a compound believed to be the metal–metal-bonded dimer [Rh(salen)(py)]2.Keywords
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