Abstract
The temperature dependence curves of the peak height, frequency, and half-width of the infrared intermolecular combination band absorbing at 1555 cm−1 in liquid D2O has been observed to behave sigmoidally between 5 and 70 °C. No evidence of sharp discontinuities has been obtained but inflection points in the rather broad temperature interval of about 25 to 40 °C have been observed. Results are discussed in terms of structural changes occurring in the liquid.

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