The reactivity of p-nitrophenyl esters with surfactants in nonaqueous solvents. I. p-Nitrophenyl acetate in benzene solutions of dodecylammonium propionate
- 1 January 1980
- journal article
- research article
- Published by CSIRO Publishing in Australian Journal of Chemistry
- Vol. 33 (4) , 757-770
- https://doi.org/10.1071/ch9800757
Abstract
The rate of decomposition of p-nitrophenyl acetate, pnpa, in benzene in the presence of dodecyl-ammonium propionate, dap, has been measured at temperatures between 288 and 308 K. The proposed rate equation consists of a term arising from micellar catalysis and a term arising from a bimolecular reaction between the ester and the components of dap. Arrhenius parameters have been estimated for the two reaction modes. Literature data related to similar reactions have been reviewed.Keywords
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