The importance of peripheral association for vitamin B12catalysed methylmalonyl–succinyl-rearrangement
- 1 January 1994
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 835-836
- https://doi.org/10.1039/c39940000835
Abstract
The rearrangement of methylmalonyl to succinyl radicals becomes an efficient process, when the reaction is performed in a protic solvent with both the vitamin B12-derived catalyst and the substrate carrying a C18 instead of a C2 alkyl chain.Keywords
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