Amplification of a cyclic mixed-metalloporphyrin tetramer from a dynamic combinatorial library through orthogonal metal coordinationElectronic supplementary information (ESI) available: Fig. S1–3: 1H NMR, 1H–1H COSY and 1H–1H NOESY spectra of (4,4′-bipy)⊂[(Zn-1)2/(Rh-2)2] at 300 K. See http://www.rsc.org/suppdata/cc/b1/b111019p/
- 13 February 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 5,p. 524-525
- https://doi.org/10.1039/b111019p
Abstract
A cyclic porphyrin tetramer, consisting of two bis-phosphine substituted zinc(II) porphyrin units and two Rh(III)TPP units, is selected and amplified virtually quantitatively from a dynamic combinatorial library using 4,4′-bipy as a scaffold and using orthogonal binding modes.Keywords
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