Lead tetraacetate oxidation of hindered alicyclic ketoximes

15 March 1970

journal article
Published by Canadian Science Publishing in Canadian Journal of Chemistry

Vol. 48 (6) , 966-969
https://doi.org/10.1139/v70-158

Abstract

Lead tetraacetate oxidation of 2,2,6,6-tetramethylcyclohexanone oxime and structurally related ketoximes caused C—C bond fission to yield acetyl hydroxamates. Severely hindered ketoximes gave nitrile oxides as intermediates which were trapped by 1,3-dipolar cycloaddition reaction.

Keywords

DIPOLAR CYCLOADDITION
CYCLOADDITION REACTION
LEAD TETRAACETATE
STRUCTURALLY
TETRAACETATE OXIDATION
RELATED KETOXIMES
ACETYL HYDROXAMATES
HINDERED KETOXIMES

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