Medium Effects on the NMR and Thermodynamic Properties of 1,1,2,2-Tetrabromofluoroethane
- 1 January 1968
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 48 (1) , 285-291
- https://doi.org/10.1063/1.1667917
Abstract
Chemical shifts, coupling constant, free energy, and free energy of activation for 1,1,2,2-tetrabromofluoroethane have been found to depend on temperature and solvent. The results can be explained qualitatively using the “reaction-field” model. Vapor-phase values for the different thermodynamic and NMR properties of the molecule have been estimated. Theory for calculating NMR spectra of two exchanging AX systems has been presented.Keywords
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