Neutron inelastic scattering studies on the hydrogen dihalides
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
- Vol. 69, 1477-1485
- https://doi.org/10.1039/f29736901477
Abstract
In this paper we report the results of an examination, both by time of flight, energy-gain inelastic neutron scattering, and by energy-loss inelastic neutron scattering spectroscopy of the vibrational modes of a very wide range of bihalide salts (e.g. NaHF2, KHF2, CsHCl2, CsHClBr, CsHBr2, CsHClI, (CD3)3NC2D5HCl2, (CD3)4NHCl2, CsCl⅓(H3O+HCl– 2), CsBr⅓(H3O+HBr– 2). The neutron scattering spectra serve as a diagnostic as to whether the bihalide ion is centrosymmetric or not. In all cases they permit an unequivocal identification of the bending mode of the bihalide ions.Keywords
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