Biomimetic synthesis of (±)-chrysomelidial, (±)-dehydroiridodial, and (±)-iridodial
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 13,p. 1020-1021
- https://doi.org/10.1039/c39870001020
Abstract
Treatment of 10-oxocitral (3), a key intermediate for iridoid biosynthesis, with 50% aqueous formic acid yielded (±)-chrysomelidial (5) and (±)-dehydroiridodial (6), while reduction of (3) or (5) and (6) in 70% aqueous formic acid with the coenzyme model (8) gave rise to (±)-iridodial (4).Keywords
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