Reaction of tris(triethylphosphine)trimethylsilyldiazomethylrhodium(I) with isocyanides. Synthesis and X-ray structure of the first 1H-1,2,3-triazolato complex with a metal–carbon bond
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 809-810
- https://doi.org/10.1039/c39910000809
Abstract
Two new C-bonded 1H-1,2,3-triazolato rhodium(I) compounds have been synthesized from the 1,3-dipolar cycloaddition of the diazo complex [Rh(PEt3)3{C(N2)SiMe3}] with isocyanides RNC (R = But and Bun).Keywords
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