Synthesis and evaluation of Co–P and Co–As organometallics as precursors for metal pnictides
- 1 September 1988
- journal article
- Published by American Vacuum Society in Journal of Vacuum Science & Technology B
- Vol. 6 (5) , 1553-1556
- https://doi.org/10.1116/1.584213
Abstract
The compounds [Co(CO)3XEt3]2,X=P,As, have been evaluated as possible precursors for the deposition of the cobaltpnictides, CoX. Thermogravimetric analysis and x‐ray diffraction reveal loss of the 1:1 Co:X stoichiometry of the starting material upon thermal decomposition. The decomposition products consist of mixed Co and Co2X phases.Keywords
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