Preparation of Cationic Complexes [Rh(diolefin)L2]C104and Their Carbonylation Reactions
- 1 January 1979
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 9 (6) , 577-584
- https://doi.org/10.1080/00945717908069780
Abstract
The addition of stoichiometric amounts of triphenylarsine or triphenylstibine to [Rh(diolefin)2]ClO4 or [Rh (diolefin) (Me2CO)x]ClO4 leads to the formation of complexes of the [Rh (diolefin)L2]ClO4 type. Normal pressure carbonylation yields pentacoordinated [Rh (diolefin) (AsPh3)2CO]ClO4 or, respectively, tetracoordinated [Rh (CO)2 (SbPh3)2]ClO4 complexes.Keywords
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