Arylamido and aryloxy complexes of nitrosyl[tris(3,5-dimethylpyrazolyl)borato]molybdenum, some mixed alkoxy/aryloxy and aryloxy/monoalkylamido species, and the structures of [Mo{HB(3,5-Me2C3N2H)3}(NO)I(NHC6H4R-p)](R = Me and OMe)
- 1 January 1983
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 1,p. 81-89
- https://doi.org/10.1039/dt9830000081
Abstract
The complexes [Mo{HB(Me2pz)3}(NO)I(NHR)][Me2pz = 3,5-dimethylpyrazolyl; R = Ph, C10H7(2-naphthyl), C6H4X-p where X = Me, Et, OMe, OEt, F, CI, Br, I, CO2Me, NO2, or CN], [Mo{HB(Me2pz)3}(NO)I(0R)](R = Ph, C6H4Me-p, and C6H4CN-p) and [Mo{HB(Me2pz)3}XY](X = Y = OPh; X = OPh, Y = OMe, OEt, or NHMe) have been prepared and characterised spectroscopically. The crystal and molecular structures of [Mo{HB(Me2pz)3}(NO)I(NHC6H4R-p)](R = Me and OMe) have been determined crystallographically.Keywords
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