Benzylic azide functionalization of tautomeric o-acyl-benzoic acid, -benzamide, and -nicotinic acid derivatives, and thermal decomposition of the derived azides
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 8,p. 2149-2154
- https://doi.org/10.1039/p19880002149
Abstract
A series of benzylic azido compounds were prepared by the reactions of o-acyl-benzoic acids and -benzamides and pyridine analogues with sodium azide, diphenylphosphoryl azide, and trimethylsilyl azide. Thermal decomposition of the derived benzylic azides afforded three types of rearrangement products. The selectivity of rearrangement depended on the migratory aptitude of substituents and on stereoelectronic factors.This publication has 0 references indexed in Scilit: