Catalysis of the Electroreduction of Allyl Chloride by Cobalt 2,2′‐Bipyridine Complexes
- 1 August 1978
- journal article
- Published by The Electrochemical Society in Journal of the Electrochemical Society
- Vol. 125 (8) , 1232-1235
- https://doi.org/10.1149/1.2131655
Abstract
The electrochemical reduction of allyl chloride is strongly catalyzed in the presence of cobalt complexes of 2,2′‐bipyridine. A prominent reaction product of the catalyzed reduction is 1,5‐hexadiene. Voltammetry, coulometry, and gas chromatographic data are presented and analyzed and a mechanistic scheme proposed to account for the catalytic action of the cobalt‐2,2′‐bipyridine complexes.Keywords
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