Achieving new lanthanide chemistry within the tetracyclopentadienyl cavity formed by two (C5Me5)2Ln moieties
- 1 February 1993
- journal article
- Published by Elsevier in Journal of Alloys and Compounds
- Vol. 192 (1-2) , 205-210
- https://doi.org/10.1016/0925-8388(93)90231-b
Abstract
No abstract availableKeywords
This publication has 26 references indexed in Scilit:
- Reactivity of samarium complex [(C5Me5)2Sm(.mu.-H)]2 in ether and arene solvents. X-ray crystal structures of the internally metalated complex (C5Me5)2Sm(.mu.-H)(.mu.-CH2C5Me4)Sm(C5Me5), the benzyl complex (C5Me5)2Sm(CH2C6H5)(THF), and the siloxide complex [(C5Me5)2Sm(THF)]2(.mu.-OSiMe2OSiMe2O)Organometallics, 1991
- Reactivity of (C5Me5)2Sm and related species with alkenes: synthesis and structural characterization of a series of organosamarium allyl complexesJournal of the American Chemical Society, 1990
- Isolation and x-ray crystal structure of the first dinitrogen complex of an f-element metal, [(C5Me5)2Sm]2N2Journal of the American Chemical Society, 1988
- Synthetic, structural, and reactivity studies of the reduction and carbon monoxide derivatization of azobenzene mediated by divalent lanthanide complexesJournal of the American Chemical Society, 1988
- Insertion of two carbon monoxide moieties into an alkene double bond to form a RCH:C(O)C(O):CHR2- unit via organosamarium activationJournal of the American Chemical Society, 1988
- The organometallic Chemistry of the lanthanide elements in low oxidation statesPolyhedron, 1987
- Synthesis and X-ray crystal structure of [(C5Me5)2Sm]2C4Ph2, a samarium η2-complex derived from an alkyneJournal of the Chemical Society, Chemical Communications, 1987
- Facile stereospecific synthesis of a dihydroxyindenoindene unit from an alkyne and carbon monoxide via samarium-mediated carbon monoxide and CH activationJournal of the American Chemical Society, 1986
- Reductive homologation of carbon monoxide to a ketenecarboxylate by a low-valent organolanthanide complex: synthesis and x-ray crystal structure of [(C5Me5)4Sm2(O2CCCO)(THF)]2Journal of the American Chemical Society, 1985
- Organolanthanide hydride chemistry. 3. Reactivity of low-valent samarium with unsaturated hydrocarbons leading to a structurally characterized samarium hydride complexJournal of the American Chemical Society, 1983