Two-dimensional diffraction from enantiopure and racemic monolayers of [Ru(bpy)3]2+ intercalated into synthetic fluorohectorite

Abstract
While for intercalation compounds of natural smectites 2D long range order of the interlamellar space was never observed, in-plane order can be detected using a homogeneously charged synthetic fluorohectorite as host material. With these intercalates distinct 2D structures for enantiopure and racemic [Ru(bpy)3]2+-interlayers, as previously predicted by atomistic simulations, can now be proven experimentally.

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