Heterocycles in organic synthesis. Part 22. The conversion of amines to thiocarbonate esters and thiocyanates
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 8,p. 1953-1956
- https://doi.org/10.1039/p19790001953
Abstract
Primary amines with 2,4,6-triphenylpyrylium perchlorate give 1-substituted pyridinium perchlorates which with potassium ethyl xanthate readily produce S-alkyl-O-ethyl dithiocarbonates. Primary amines with 2.4,6-triphenylpyrylium thiocyanate form 1-substituted- 2,4,6-triphenylpyridinium thiocyanates which thermolyse smoothly to the corresponding alkyl and aralkyl thiocyanatesThis publication has 0 references indexed in Scilit: