Rapid and mild deoxygenation of organoheteroatom oxides with the efficient electron transfer system SmI₂–tetrahydrofuran–hexamethylphosphoric triamide

1 January 1989

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 5,p. 298-299
https://doi.org/10.1039/c39890000298

Abstract

A variety of organoheteroatom oxides such as sulphoxides, sulphones, N-oxides, a phosphine oxide, and an organo tin oxide were rapidly deoxygenated at room temperature by using a stoicheiometric amount of SmI₂ in tetrahydrofuran–hexamethylphosphoric triamide.

Keywords

ELECTRON TRANSFER

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Rapid and mild deoxygenation of organoheteroatom oxides with the efficient electron transfer system SmI2–tetrahydrofuran–hexamethylphosphoric triamide

Abstract

Keywords

Rapid and mild deoxygenation of organoheteroatom oxides with the efficient electron transfer system SmI₂–tetrahydrofuran–hexamethylphosphoric triamide