A New Synthesis of Thioamides and Dithiocarbamates from Organolithium Derivatives
- 1 January 1993
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1993 (05) , 483-484
- https://doi.org/10.1055/s-1993-25888
Abstract
The reaction of organolithium derivatives with thiuram monosulfides gives a convenient method for the synthesis of both aromatic and aliphatic thioamides in good yields. In our hands, the reaction of organolithium derivatives with tetramethylthiuram disulfide gave only dithiocarbamates and not a mixture of these and thioamides.Keywords
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