Origin of Cu and Zn L2- and L3-M45M45 Auger satellites: Breakdown of the sudden approximation

Abstract
Initiating Auger transitions using tunable monochromatic x rays from synchrotron, we show that the satellite intensities in L2 M45 M45 and L3 M45 M45 spectra of Cu and Zn increase with increasing photon energies up to about 200 eV above the thresholds. This indicates a pronounced influence of the history of the core-hole generation on Auger spectra, in sharp contrast to the universally accepted belief, and suggests a breakdown of the sudden approximation. Details of the photon energy dependence of the satellite intensity provide a new interpretation for the origin of the satellite.