Reactions between trimethylenemethane metal complexes and the carbon–nitrogen double bond: nickel and palladium catalysed synthesis of pyrrolidines

Abstract
The d10 nickel complex [Ni{P(OEt)3}4] catalyses the cycloaddition of trimethylenemethane to the CN double bond of an imine to afford a high-yield synthesis of 4-methylenepyrrolidines.

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