A facile digermene-to-germylgermylene rearrangement; bulky germylene insertion into the Si–H bond
- 1 January 1992
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1484-1485
- https://doi.org/10.1039/c39920001484
Abstract
The thermolysis of hexamesitylcyclotrigermane 1 in the presence of triethylsilane at 105 °C yields dimesityl(triethylsilyl)germane 2 and 1,1,1,2-tetramesityl(2-triethylsilyl)digermane 3; the molecular structure of 3 has been determined by X-ray crystallography.Keywords
This publication has 13 references indexed in Scilit:
- Molecular structures of a siladigermirane and a cyclotrigermaneOrganometallics, 1992
- Strained‐Ring and Double‐Bond Systems Consisting of the Group 14 Elements Si, Ge, and SnAngewandte Chemie International Edition in English, 1991
- Molecular structures and reactivities of digermiranes and azadigermiridinesOrganometallics, 1990
- Concerning the silicon-germanium bond. The structures of isomeric Ph3EE′Me3, E = Ge, E′ = Si and E = Si, E′ = GeJournal of Organometallic Chemistry, 1990
- Telluradigermiranes. A novel three-membered ring system containing telluriumJournal of the Chemical Society, Chemical Communications, 1990
- Dimethylgermylene Insertion into the Si–H BondChemistry Letters, 1989
- Thermolysis of cyclotrigermane: simple preparation of digermetanes containing a germanium–germanium bondJournal of the Chemical Society, Chemical Communications, 1989
- Organometalloidal derivatives of the transition metalsJournal of Organometallic Chemistry, 1986
- Pyrolysis of silylphosphine and germylsilane and the formation of phosphylene (PH)Inorganic Chemistry, 1973
- Germanium atoms. Reactions with germane and silaneJournal of the American Chemical Society, 1969