Intercollisional Interference in the S Lines of H2–He Mixtures

Abstract
Further experimental results on the pressure induced spectrum of normal H2–He in the region of the S(1) branch of the fundamental band are presented. These results show a well-defined minimum at the transition frequency of the free molecule. The S line is found to be the sum of two components. One of these is of essentially the same nature as the Q branch and should therefore show a pronounced intercollisional interference minimum. The second component shows the usual quadrupolar line shape without a minimum. Finally, a value for the strength parameter characterizing the short range component of the induced dipole moment is determined.