Metal-ion controlled helicity of an 18-membered hexaaza tetraamine macrocycle
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 2399-2400
- https://doi.org/10.1039/c39940002399
Abstract
Complexes of ZnII, CdII and LaIII with a novel hexadentate tetraamine macrocycle L1 are prepared and their X-ray structure analyses demonstrate the helicity of the tetraamine macrocycle is controlled by the metal ion size and its prefered coordination.Keywords
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