The influence of carbanion orbital orientation and charge distribution on the structures of polylithium compounds
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 22,p. 1495-1496
- https://doi.org/10.1039/c39840001495
Abstract
Symmetrical (C2v) double bridging, commonly exhibited by 1,4-dilithium compounds e.g. in (1) and (2), is not favoured in (4) and (5) since charge deloclization in the dianion, hybridization, and orbital orientation effects are more important than quadrupole-like electrostatic interactions (3).Keywords
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