[Cu₆S₁₇]^2–, a novel binary discrete polynuclear Cu^Icomplex with several interesting structural features: the arrangement of the metal atoms and co-ordination of ligands

Abstract

The structure of [PPh₄]₂[Cu₆S₁₇], obtained from Cu(acac)₂(Hacac = acetylacetone) and PPh₄Br in an ethanol solution of polysulphide, contains an unusual arrangement of metal atoms (which can only approximately be described as two distorted Cu tetrahedral sharing one edge) and novel ligand co-ordination of polysulphide (S₄ ^2– and S₅ ^2–) ions.

Keywords

STRUCTURAL
SUP
PPH
DISTORTED
ETHANOL
ACETYLACETONE
DISCRETE
EDGE

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[Cu6S17]2–, a novel binary discrete polynuclear CuIcomplex with several interesting structural features: the arrangement of the metal atoms and co-ordination of ligands

Abstract

Keywords

[Cu₆S₁₇]^2–, a novel binary discrete polynuclear Cu^Icomplex with several interesting structural features: the arrangement of the metal atoms and co-ordination of ligands