Pyrazole and benzothiazole palladacycles: stable and efficient catalysts for carbon–carbon bond formation
- 1 January 2000
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 20,p. 2053-2054
- https://doi.org/10.1039/b005452f
Abstract
Cyclopalladated phosphine free pyrazole complexes 1 and benzothiazole complexes 2 are excellent catalysts for the Heck vinylation of aryl iodides and termolecular queuing cascades, leading to turnover numbers of >106 in some cases, at moderate temperatures; these catalysts show high thermal stability and are not sensitive to moisture and air.Keywords
This publication has 0 references indexed in Scilit: