The Synthesis of 4-O-α-D-Glucopyranosyl-L-rhamnopyranose
- 15 February 1974
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 52 (4) , 681-683
- https://doi.org/10.1139/v74-105
Abstract
4-O-α-D-Glucopyranosyl-L-rhamnose has been synthesized in 40% overall yield by condensation of 2-O-benzyl-3,4,6-tri-O-p-nitrobenzoyl-β-D-glucopyranosyl bromide with methyl 2,3-O-isopropylidene-α-L-rhamnopyranoside in nitromethane using mercuric cyanide as acid acceptor. The methyl glycoside hexaacetate was obtained crystalline.Keywords
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