THE NOVEL TYPE STRUCTURE OF Δ-CIS-α-[(1R,2R) -N,N′-BIS(2-PYRIDYLMETHYL)-1,2-CYCLOHEXANEDIAMINE]DICHLOROCHROMIUM(III) CATION

Abstract
The molecular structure of Δ-CIS-α-[CrCl2(RR-picchxn)]+ was determined by the X-ray structure analysis (RR-picchxn = (1R,2R)-N,N′-bis(2-pyridylmethyl)-1,2-cyclohexanediamine). The terminal chelate ring formed by the coordination of equatorially-oriented substituent on the secondary nitrogen atom is of novel type.

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